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Issue 37, 2011
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Visualising the carboxylate shift at a bioinspired diiron(II) site in the solid state

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Abstract

A novel pyrazolate-based diiron(II) complex shows five different binding modes of exogenous carboxylate ligands in a single crystal structure. Temperature dependent X-ray data reveal thermally induced disorder due to carboxylate dynamics that resemble the carboxylate shift, as it is known from various diiron enzyme active sites.

Graphical abstract: Visualising the carboxylate shift at a bioinspired diiron(ii) site in the solid state

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Publication details

The article was received on 23 Jun 2011, accepted on 25 Jul 2011 and first published on 15 Aug 2011


Article type: Communication
DOI: 10.1039/C1CC13756E
Citation: Chem. Commun., 2011,47, 10428-10430
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    Visualising the carboxylate shift at a bioinspired diiron(II) site in the solid state

    B. Burger, S. Dechert, C. Große, S. Demeshko and F. Meyer, Chem. Commun., 2011, 47, 10428
    DOI: 10.1039/C1CC13756E

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