Acetophenone hydrogenation over a Pd catalyst in the presence of H2O and CO2

Norihito Hiyoshi; Osamu Sato; Aritomo Yamaguchi; Masayuki Shirai

doi:10.1039/C1CC13130C

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Acetophenonehydrogenation over a Pdcatalyst in the presence of H₂O and CO₂†

Norihito Hiyoshi,^a Osamu Sato,^a Aritomo Yamaguchi^a and Masayuki Shirai*^a

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* Corresponding authors

^a Research Center for Compact Chemical System, National Institute of Advanced Industrial Science and Technology (AIST), 4-2-1 Nigatake, Miyagino, Sendai, Japan
E-mail: m.shirai@aist.go.jp
Fax: +81 22 237 5224

Abstract

The addition of carbon dioxide and water enhances acetophenone hydrogenation activity over an activated carbon-supported palladium catalyst, and 1-phenylethanol can be easily recovered without distillation and neutralization. Two liquid phases (water and acetophenone) are indispensable for enhancement of the hydrogenation rate.

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Article information

DOI: https://doi.org/10.1039/C1CC13130C
Article type: Communication
Submitted: 27 May 2011
Accepted: 15 Sep 2011
First published: 26 Sep 2011

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Chem. Commun., 2011,47, 11546-11548

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Acetophenone hydrogenation over a Pd catalyst in the presence of H₂O and CO₂

N. Hiyoshi, O. Sato, A. Yamaguchi and M. Shirai, Chem. Commun., 2011, 47, 11546 DOI: 10.1039/C1CC13130C

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