Beijing National Laboratory of Molecular Science, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
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Chem. Commun., 2011,47, 8049-8051
14 May 2011,
01 Jun 2011
First published online
16 Jun 2011
A pair of enantiopure star-shaped FeIII4 clusters were constructed from simple chiral ligands. AC field frequency dependence and a hysteresis loop, which are very important features of SMMs, were observed. Circular dichroism (CD) spectra demonstrated that the chirality was successfully transferred from the ligand to the coordination environment of Fe3+ ions.
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