Issue 32, 2011
From the journal:

Chemical Communications

A single tripodal ligand stabilizing three different oxidation states (II, III, and IV) of manganese†

Yukinari Sunatsuki,a   Yukana Kishima,a   Tamami Kobayashi,a   Tomoka Yamaguchi,a   Takayoshi Suzuki,a   Masaaki Kojima,*a   J. Krzystekb  and  Markku R. Sundbergc  

* Corresponding authors

a Department of Chemistry, Faculty of Science, Okayama University, 3-1-1 Tsushima-naka, Okayama 700-8530, Japan
E-mail: mkojima@ksn.biglobe.ne.jp
Fax: (+81)86-255-3712

b National High Magnetic Field Laboratory, Florida State University, Tallahassee, Florida 32310, USA

c Department of Chemistry, Laboratory of Inorganic Chemistry, University of Helsinki, POB 55, Finland

Abstract

A series of mononuclear MnII, MnIII, and MnIV complexes was prepared using a single tripodal ligand (H3L). Addition of a cation (NH4+, K+, Na+) to [MnIIIL] showed a pronounced effect on the redox potentials. Different variants of Jahn–Teller distortion, axial elongation and compression, were observed in the MnIII complexes.

Graphical abstract: A single tripodal ligand stabilizing three different oxidation states (II, III, and IV) of manganese

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Article information

DOI
https://doi.org/10.1039/C1CC12418H
Article type
Communication
Submitted
26 Apr 2011
Accepted
24 Jun 2011
First published
13 Jul 2011

Chem. Commun., 2011,47, 9149-9151

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A single tripodal ligand stabilizing three different oxidation states (II, III, and IV) of manganese

Y. Sunatsuki, Y. Kishima, T. Kobayashi, T. Yamaguchi, T. Suzuki, M. Kojima, J. Krzystek and M. R. Sundberg, Chem. Commun., 2011, 47, 9149 DOI: 10.1039/C1CC12418H

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