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Issue 27, 2011
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Manganese(III)-mediated phosphinoyl radical reactions for stereoselective synthesis of phosphinoylated tetrahydronaphthalenes

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Abstract

Reactions of diphenylphosphinoyl radicals with 5-aryl-2-pentenoates or β-phenylethylene styrenes generate trans-substituted tetrahydronaphthalenes through a cascade reaction sequence.

Graphical abstract: Manganese(iii)-mediated phosphinoyl radical reactions for stereoselective synthesis of phosphinoylated tetrahydronaphthalenes

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Publication details

The article was received on 21 Apr 2011, accepted on 12 May 2011 and first published on 01 Jun 2011


Article type: Communication
DOI: 10.1039/C1CC12343B
Citation: Chem. Commun., 2011,47, 7875-7877
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    Manganese(III)-mediated phosphinoyl radical reactions for stereoselective synthesis of phosphinoylated tetrahydronaphthalenes

    X. Pan, L. Wang, J. Zou and W. Zhang, Chem. Commun., 2011, 47, 7875
    DOI: 10.1039/C1CC12343B

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