Living/controlled free radical copolymerization of chlorotrifluoroethene and butyl vinyl ether under 60Co γ-ray irradiation in the presence of S-benzyl O-ethyl dithiocarbonate

Lei Liu; Dan Lu; Hu Wang; Qibao Dong; Pucheng Wang; Ruke Bai

doi:10.1039/C1CC11749A

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Living/controlled free radical copolymerization of chlorotrifluoroethene and butyl vinyl ether under ⁶⁰Co γ-ray irradiation in the presence of S-benzyl O-ethyl dithiocarbonate†

Lei Liu,^a Dan Lu,^a Hu Wang,^a Qibao Dong,^a Pucheng Wang^a and Ruke Bai*^a

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* Corresponding authors

^a CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026, People's Republic of China
E-mail: bairk@ustc.edu.cn
Fax: 0086-551-3631760
Tel: 0086-551-3600722

Abstract

Living/controlled free radical copolymerization of chlorotrifluoroethene and butyl vinyl ether has been successfully achieved at room temperature under ⁶⁰Co γ-ray irradiation in the presence of S-benzyl O-ethyl dithiocarbonate. The alternating and block copolymers have been obtained with well-defined molecular weights and narrow molecular weight distributions.

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Article information

DOI: https://doi.org/10.1039/C1CC11749A
Article type: Communication
Submitted: 28 Mar 2011
Accepted: 19 May 2011
First published: 07 Jun 2011

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Chem. Commun., 2011,47, 7839-7841

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Living/controlled free radical copolymerization of chlorotrifluoroethene and butyl vinyl ether under ⁶⁰Co γ-ray irradiation in the presence of S-benzyl O-ethyl dithiocarbonate

L. Liu, D. Lu, H. Wang, Q. Dong, P. Wang and R. Bai, Chem. Commun., 2011, 47, 7839 DOI: 10.1039/C1CC11749A

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Chemical Communications