Chromium chains as polydentate fluoride ligands for lanthanides

Andrew McRobbie; Asad R. Sarwar; Steven Yeninas; Harriott Nowell; Michael L. Baker; David Allan; Marshall Luban; Christopher A. Muryn; Robin G. Pritchard; Ruslan Prozorov; Grigore A. Timco; Floriana Tuna; George F. S. Whitehead; Richard E. P. Winpenny

doi:10.1039/C1CC11516B

Chromium chains as polydentate fluoride ligands for lanthanides†‡

Andrew McRobbie,^a Asad R. Sarwar,^a Steven Yeninas,^b Harriott Nowell,^c Michael L. Baker,^ad David Allan,^c Marshall Luban,^b Christopher A. Muryn,^a Robin G. Pritchard,^a Ruslan Prozorov,*^b Grigore A. Timco,^a Floriana Tuna,^a George F. S. Whitehead^a and Richard E. P. Winpenny*^a

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^a The Lewis Magnetism Laboratory, School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester, UK
E-mail: richard.winpenny@manchester.ac.uk
Tel: +44(0)161 275 4654

^b Department of Physics and Astronomy and Ames Laboratory, Iowa State University, Ames, Iowa 50011, USA

^c Diamond Light Source, Harwell Science and Innovation Campus, Didcot, UK

^d Institut Laue-Langevin, BP 156, 6 rue Jules Horowitz, Grenoble Cedex 9, France

Abstract

Hexametallic chromium(III) chains can act as fluoride donor ligands to lanthanide ions giving {(Cr₆)Ln_x}_n complexes; preliminary spectroscopic studies are reported.

This article is part of the themed collection: Supramolecular Chemistry

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Chromium chains as polydentate fluoride ligands for lanthanides†‡

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Chromium chains as polydentate fluoride ligands for lanthanides

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