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Issue 28, 2011
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The two spin states of an end-on copper(II)-superoxide mimic

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Abstract

The reaction of nitrosobenzene with copper(I) complexes of a tetradentate ligand led to two novel species that are best described as copper(II) complexes of an O-bonded nitrosobenzyl radical anion, in either the singlet or the triplet spin-state. Both states were characterized by crystal structures, magnetic measurements and DFT calculations.

Graphical abstract: The two spin states of an end-on copper(ii)-superoxide mimic

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Publication details

The article was received on 09 Mar 2011, accepted on 01 Jun 2011 and first published on 16 Jun 2011


Article type: Communication
DOI: 10.1039/C1CC11381J
Citation: Chem. Commun., 2011,47, 8055-8057
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    The two spin states of an end-on copper(II)-superoxide mimic

    M. S. Askari, B. Girard, M. Murugesu and X. Ottenwaelder, Chem. Commun., 2011, 47, 8055
    DOI: 10.1039/C1CC11381J

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