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Highly enantioselective zinc/BINOL-catalyzed alkynylation of α-ketoimine ester: a new entry to optically active quaternary α-CF3 α-amino acids

Gaochao Huang,a   Jie Yangb and   Xingang Zhang*a  
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a
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 3, 45 Lingling Road, Shanghai 200032, China
E-mail: xgzhang@mail.sioc.ac.cn;
Fax: (+86)-21-6416-6128 ;
Tel: (+86)-21-5492-5333
b
Graduate School of Southwest Petroleum University, 8 Xindu Avenue, Chengdu 610065, China
Chem. Commun., 2011,47, 5587-5589

DOI: 10.1039/C1CC10403A
Received 20 Jan 2011, Accepted 10 Mar 2011
First published online 05 Apr 2011
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