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Issue 14, 2011
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Functionalization of the corrole ring: the role of isocorrole intermediates

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Abstract

Bromination of 3-nitro-5,10,15-triarylcorrole selectively provides two regioisomers, depending on the reaction pathway. An isocorrole species is the key intermediate to drive the reaction towards the 2-Br-17-nitro regioisomer.

Graphical abstract: Functionalization of the corrole ring: the role of isocorrole intermediates

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Publication details

The article was received on 29 Dec 2010, accepted on 09 Feb 2011 and first published on 24 Feb 2011


Article type: Communication
DOI: 10.1039/C0CC05837H
Citation: Chem. Commun., 2011,47, 4243-4245
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    Functionalization of the corrole ring: the role of isocorrole intermediates

    L. Tortora, S. Nardis, F. R. Fronczek, K. M. Smith and R. Paolesse, Chem. Commun., 2011, 47, 4243
    DOI: 10.1039/C0CC05837H

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