Issue 11, 2011

Copper-catalyzed synthesis of alkynylphosphine derivatives: unprecedented use of nucleophilic phosphorus compounds

Abstract

A new and smooth approach towards alkynylphosphine derivatives is described. It relies on the unprecedented catalytic coupling of secondary phosphine boranes with alkynyl bromides using the CuI/1,10-phenanthroline couple.

Graphical abstract: Copper-catalyzed synthesis of alkynylphosphine derivatives: unprecedented use of nucleophilic phosphorus compounds

Supplementary files

Article information

Article type
Communication
Submitted
27 Oct 2010
Accepted
10 Jan 2011
First published
25 Jan 2011

Chem. Commun., 2011,47, 3239-3241

Copper-catalyzed synthesis of alkynylphosphine derivatives: unprecedented use of nucleophilic phosphorus compounds

E. Bernoud, C. Alayrac, O. Delacroix and A. Gaumont, Chem. Commun., 2011, 47, 3239 DOI: 10.1039/C0CC04645K

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