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Chloride ion-catalyzed generation of difluorocarbene for efficient preparation of gem-difluorinated cyclopropenes and cyclopropanes

Fei Wang,a   Wei Zhang,a   Jieming Zhu,a   Huaifeng Li,b   Kuo-Wei Huang*b and   Jinbo Hu*a  
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Corresponding authors
a
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Ling-Ling Road, Shanghai 200032, China
E-mail: jinbohu@sioc.ac.cn
b
KAUST Catalysis Center and Division of Chemical and Life Sciences and Engineering, King Abdullah University of Science and Technology, Thuwal 23955-6900, Saudi Arabia
E-mail: hkw@kaust.edu.sa
Chem. Commun., 2011,47, 2411-2413

DOI: 10.1039/C0CC04548A
Received 21 Oct 2010, Accepted 23 Nov 2010
First published online 20 Dec 2010
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