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Issue 9, 2011
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Observation of a two-dimensional halogen-bonded cocrystal at sub-monolayer coverage using synchrotron X-ray diffraction

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Abstract

The formation of two-dimensional halogen-bonded layers of 4,4′-bipyridyl and 1,4-diiodotetrafluorobenzene was observed on a graphite surface at sub-monolayer coverage using synchrotron X-ray diffraction; the use of the diffraction technique enabled, for the first time, the measurement of I⋯N halogen bonding distances in a two-dimensional cocrystal and the identification of the halogen bonding interaction in the monolayer.

Graphical abstract: Observation of a two-dimensional halogen-bonded cocrystal at sub-monolayer coverage using synchrotron X-ray diffraction

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Publication details

The article was received on 14 Oct 2010, accepted on 02 Dec 2010 and first published on 23 Dec 2010


Article type: Communication
DOI: 10.1039/C0CC04400H
Citation: Chem. Commun., 2011,47, 2526-2528
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    Observation of a two-dimensional halogen-bonded cocrystal at sub-monolayer coverage using synchrotron X-ray diffraction

    S. M. Clarke, T. Friščić, W. Jones, A. Mandal, C. Sun and J. E. Parker, Chem. Commun., 2011, 47, 2526
    DOI: 10.1039/C0CC04400H

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