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Issue 9, 2011
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Crystal structures, EPR and magnetic properties of 2-ClC6H4CNSSN˙ and 2,5-Cl2C6H3CNSSN˙

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Abstract

The β-sheet structure associated with chlorinated aromatics (dClCl ≈ 4.0 Å) has been implemented to drive formation of π-stacked structures of dithiadiazolyl radicals. Both title compounds exhibit an increase in paramagnetism above 150 K but solid-state EPR studies indicate that the origin of the paramagnetism in these two systems is different.

Graphical abstract: Crystal structures, EPR and magnetic properties of 2-ClC6H4CNSSN˙ and 2,5-Cl2C6H3CNSSN˙

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Publication details

The article was received on 08 Oct 2010, accepted on 14 Dec 2010 and first published on 12 Jan 2011


Article type: Communication
DOI: 10.1039/C0CC04296J
Citation: Chem. Commun., 2011,47, 2532-2534
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    Crystal structures, EPR and magnetic properties of 2-ClC6H4CNSSN˙ and 2,5-Cl2C6H3CNSSN˙

    A. Alberola, E. Carter, C. P. Constantinides, D. J. Eisler, D. M. Murphy and J. M. Rawson, Chem. Commun., 2011, 47, 2532
    DOI: 10.1039/C0CC04296J

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