Issue 2, 2011
From the journal:

Chemical Communications

Reversible solid-state structural conversion between a three-dimensional network and a one-dimensional chain of Cu(ii) triazole coordination polymers in acidic/basic-suspensions or vapors†

Tetsuya Yamada,a   Goro Maruta*a  and  Sadamu Takeda*a  

* Corresponding authors

a Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060-0810, Japan
E-mail: stakeda@sci.hokudai.ac.jp, maruta@sci.hokudai.ac.jp
Fax: +81-11-706-4841
Tel: +81-11-706-3505

Abstract

New Cu(II) triazole coordination polymers with a 3D network were synthesized and reversible structural conversion between a 3D network and a 1D chain with color change was realized by pH controlled acidic and basic-suspensions or vapors. For each conversion process of decreasing and increasing pH, conversion was accomplished with high yield, in which the crystal before conversion played the role of a solid-state crystal template.

Graphical abstract: Reversible solid-state structural conversion between a three-dimensional network and a one-dimensional chain of Cu(ii) triazole coordination polymers in acidic/basic-suspensions or vapors

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Article information

DOI
https://doi.org/10.1039/C0CC04293E
Article type
Communication
Submitted
08 Oct 2010
Accepted
15 Nov 2010
First published
29 Nov 2010

Chem. Commun., 2011,47, 653-655

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Reversible solid-state structural conversion between a three-dimensional network and a one-dimensional chain of Cu(II) triazole coordination polymers in acidic/basic-suspensions or vapors

T. Yamada, G. Maruta and S. Takeda, Chem. Commun., 2011, 47, 653 DOI: 10.1039/C0CC04293E

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