Issue 6, 2011

Palladium catalyzed ring opening of furans as a route to α,β-unsaturated aldehydes

Abstract

Furans may be ring opened via pallado-catalyzed reactions leading to α,β-unsaturated aldehydes and ketones tethered to indole and isoquinoline moieties. Besides their synthetic interest, these fragmentations bring interesting elements into the discussion around the reaction mechanisms involved in palladium C–H activations of electron-rich heterocycles.

Graphical abstract: Palladium catalyzed ring opening of furans as a route to α,β-unsaturated aldehydes

Supplementary files

Article information

Article type
Communication
Submitted
30 Sep 2010
Accepted
16 Nov 2010
First published
02 Dec 2010

Chem. Commun., 2011,47, 1887-1889

Palladium catalyzed ring opening of furans as a route to α,β-unsaturated aldehydes

L. El Kaïm, L. Grimaud and S. Wagschal, Chem. Commun., 2011, 47, 1887 DOI: 10.1039/C0CC04164E

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