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Issue 6, 2011
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Palladium catalyzed ring opening of furans as a route to α,β-unsaturated aldehydes

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Abstract

Furans may be ring opened via pallado-catalyzed reactions leading to α,β-unsaturated aldehydes and ketones tethered to indole and isoquinoline moieties. Besides their synthetic interest, these fragmentations bring interesting elements into the discussion around the reaction mechanisms involved in palladium C–H activations of electron-rich heterocycles.

Graphical abstract: Palladium catalyzed ring opening of furans as a route to α,β-unsaturated aldehydes

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Publication details

The article was received on 30 Sep 2010, accepted on 16 Nov 2010 and first published on 02 Dec 2010


Article type: Communication
DOI: 10.1039/C0CC04164E
Citation: Chem. Commun., 2011,47, 1887-1889
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    Palladium catalyzed ring opening of furans as a route to α,β-unsaturated aldehydes

    L. El Kaïm, L. Grimaud and S. Wagschal, Chem. Commun., 2011, 47, 1887
    DOI: 10.1039/C0CC04164E

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