Issue 2, 2011
From the journal:

Chemical Communications

Indium(i)-catalyzed alkyl–allyl coupling between ethers and an allylborane†

Hai Thanh Dao,a   Uwe Schneidera  and  Shū Kobayashi*a  

* Corresponding authors

a Department of Chemistry, School of Science and Graduate School of Pharmaceutical Sciences, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
E-mail: shu_kobayashi@chem.s.u-tokyo.ac.jp

Abstract

An efficient method for alkyl–allyl cross-coupling between ethers and a 9-BBN-derived allylborane catalyzed by indium(I) triflate has been developed. The allylborane proved to be essential to obtain the desired products in high yields. The reaction displayed good substrate scope including high functional group tolerance.

Graphical abstract: Indium(i)-catalyzed alkyl–allyl coupling between ethers and an allylborane

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Article information

DOI
https://doi.org/10.1039/C0CC03673K
Article type
Communication
Submitted
05 Sep 2010
Accepted
01 Nov 2010
First published
22 Nov 2010

Chem. Commun., 2011,47, 692-694

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Indium(I)-catalyzed alkyl–allyl coupling between ethers and an allylborane

H. T. Dao, U. Schneider and S. Kobayashi, Chem. Commun., 2011, 47, 692 DOI: 10.1039/C0CC03673K

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