Issue 1, 2011
From the journal:

Chemical Communications

High heat of hydrogen adsorption and guest-responsive magnetic modulation in a 3D porous pillared-layer coordination framework†‡

Arpan Hazra,a   Prakash Kanooa  and  Tapas Kumar Maji*a  

* Corresponding authors

a Molecular Materials Laboratory, Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore 560 064, India
E-mail: tmaji@jncasr.ac.in
Fax: +91 80 2208 2766
Tel: +91 80 2208 2826

Abstract

A bimetallic pillared-layer coordination framework {[Mn3(bipy)3(H2O)4][Cr(CN)6]2·2(bipy)·4(H2O)}n has been constructed using a cyanometallate anion ([Cr(CN)6]3−) and an organic linker (4,4′-bipyridyl) that provides high heat of hydrogen adsorption (∼11.5 kJ mol−1) and shows guest dependent magnetic modulation.

Graphical abstract: High heat of hydrogen adsorption and guest-responsive magnetic modulation in a 3D porous pillared-layer coordination framework

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Article information

DOI
https://doi.org/10.1039/C0CC02490B
Article type
Communication
Submitted
10 Jul 2010
Accepted
01 Nov 2010
First published
19 Nov 2010

Chem. Commun., 2011,47, 538-540

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High heat of hydrogen adsorption and guest-responsive magnetic modulation in a 3D porous pillared-layer coordination framework

A. Hazra, P. Kanoo and T. K. Maji, Chem. Commun., 2011, 47, 538 DOI: 10.1039/C0CC02490B

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