Issue 47, 2010

The (4+3)-cycloaddition reaction: heteroatom-substituted allylic cations as dienophiles

Abstract

The (4+3)-cycloaddition of allylic cations to dienes is a powerful method for the direct synthesis of seven-membered rings. Recent developments in this area have included new methods for the generation of allylic cations, diastereoselective and catalytic, enantioselective reactions, an increased understanding of the diverse mechanistic possibilities of the reaction and applications to the total synthesis of natural products and their analogues.

Graphical abstract: The (4+3)-cycloaddition reaction: heteroatom-substituted allylic cations as dienophiles

Article information

Article type
Feature Article
Submitted
02 Sep 2010
Accepted
22 Oct 2010
First published
10 Nov 2010

Chem. Commun., 2010,46, 8904-8922

The (4+3)-cycloaddition reaction: heteroatom-substituted allylic cations as dienophiles

M. Harmata, Chem. Commun., 2010, 46, 8904 DOI: 10.1039/C0CC03621H

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