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Issue 45, 2010
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Chiral magnetic metal–organic frameworks of MnII with achiral tetrazolate-based ligands by spontaneous resolution

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Abstract

The enantiomers of complex 1 (1a and 1b) have been obtained by spontaneous resolution upon crystallization in the absence of a chiral source. The enantiomeric nature of 1a and 1b was confirmed by circular dichroism (CD) spectra and theoretical investigation.

Graphical abstract: Chiral magnetic metal–organic frameworks of MnII with achiral tetrazolate-based ligands by spontaneous resolution

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Publication details

The article was received on 07 Aug 2010, accepted on 20 Sep 2010 and first published on 19 Oct 2010


Article type: Communication
DOI: 10.1039/C0CC03111A
Citation: Chem. Commun., 2010,46, 8543-8545
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    Chiral magnetic metal–organic frameworks of MnII with achiral tetrazolate-based ligands by spontaneous resolution

    X. Tong, T. Hu, J. Zhao, Y. Wang, H. Zhang and X. Bu, Chem. Commun., 2010, 46, 8543
    DOI: 10.1039/C0CC03111A

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