Issue 43, 2010
From the journal:

Chemical Communications

Excimer formation in crystalline and nanostructured coordination polymers†

Jing Chen,a   Antonia Neelsb  and  Katharina M. Fromm*a  

* Corresponding authors

a University of Fribourg, Department of Chemistry, Chemin du Musée 9, CH-1700 Fribourg, Switzerland
E-mail: katharina.fromm@unifr.ch
Fax: +41 26 300 9738
Tel: +41 26 300 8732

b CSEM, Institut de Microtechnique, Jaquet Droz 1, CH-2002 Neuchatel, Switzerland
E-mail: Antonia.neels@csem.ch
Fax: +41 32 720 5711
Tel: +41 32 720 5195

Abstract

A new anthracene-based ligand shows emission shift and decrease of excimer band upon coordination to silver ions when crystallized from methanol. Changing the solvent leads to the formation of amorphous nanowires exhibiting large emission bands before transforming into a second crystalline compound with excimer emission similar in intensity to the ligand alone.

Graphical abstract: Excimer formation in crystalline and nanostructured coordination polymers

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Article information

DOI
https://doi.org/10.1039/C0CC03011B
Article type
Communication
Submitted
03 Aug 2010
Accepted
15 Sep 2010
First published
30 Sep 2010

Chem. Commun., 2010,46, 8282-8284

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Excimer formation in crystalline and nanostructured coordination polymers

J. Chen, A. Neels and K. M. Fromm, Chem. Commun., 2010, 46, 8282 DOI: 10.1039/C0CC03011B

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