Jump to main content
Jump to site search

Issue 38, 2010
Previous Article Next Article

Quantitative synthesis and full characterization of the first isolated and stable pincer palladium(IV) complexes. Quantitative and regioselective synthesis of the C–X (X = Cl, Br) reductive elimination products

Author affiliations

Abstract

The pincer complexes [Pd(O1,N1,C1-L)X], where X = Cl, Br and L is the monoanionic ligand resulting from deprotonation of the acetyl methyl group of the monoketal of 2,6-diacetylpyridine (dap), react with excess of Cl2 or Br2 affording, quantitatively, the Pd(IV) complexes [Pd(O1,N1,C1-L)X3], which have been characterized by X-ray diffraction, and their decomposition that quantitatively affords the reductive elimination products L–X has been studied.

Graphical abstract: Quantitative synthesis and full characterization of the first isolated and stable pincer palladium(iv) complexes. Quantitative and regioselective synthesis of the C–X (X = Cl, Br) reductive elimination products

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 19 Jul 2010, accepted on 09 Aug 2010 and first published on 26 Aug 2010


Article type: Communication
DOI: 10.1039/C0CC02660C
Citation: Chem. Commun., 2010,46, 7253-7255
  •   Request permissions

    Quantitative synthesis and full characterization of the first isolated and stable pincer palladium(IV) complexes. Quantitative and regioselective synthesis of the C–X (X = Cl, Br) reductive elimination products

    J. Vicente, A. Arcas, F. Juliá-Hernández and D. Bautista, Chem. Commun., 2010, 46, 7253
    DOI: 10.1039/C0CC02660C

Search articles by author