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Issue 35, 2010
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Product-selectivity control by the nature of the catalyst: Lewis acid-catalyzed selective formation of ring-fused tetrahydroquinolines and tetrahydroazepines via intramolecular redox reaction

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Abstract

Selective synthesis of ring-fused tetrahydroquinolines and tetrahydroazepines from the same starting materials was achieved by subtle use of the oxophilic Sc(OTf)3 or carbophilic IPrAuOTf as the catalyst.

Graphical abstract: Product-selectivity control by the nature of the catalyst: Lewis acid-catalyzed selective formation of ring-fused tetrahydroquinolines and tetrahydroazepines via intramolecular redox reaction

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Publication details

The article was received on 18 Jun 2010, accepted on 02 Jul 2010 and first published on 10 Aug 2010


Article type: Communication
DOI: 10.1039/C0CC01946A
Citation: Chem. Commun., 2010,46, 6593-6595
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    Product-selectivity control by the nature of the catalyst: Lewis acid-catalyzed selective formation of ring-fused tetrahydroquinolines and tetrahydroazepines via intramolecular redox reaction

    G. Zhou and J. Zhang, Chem. Commun., 2010, 46, 6593
    DOI: 10.1039/C0CC01946A

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