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Issue 32, 2010
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Synthesis, structure, and theoretical investigation of amidinato supported 1,4-disilabenzene

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Abstract

Reaction of LSiSiL (1) (L = PhC(NtBu)2) with diphenyl alkyne gave the first example of a room temperature stable 1,4-disilabenzene. The compound was characterized by means of single crystal X-ray diffraction studies. NICS (nucleus independent chemical shift) calculations showed that the compound has some aromatic character.

Graphical abstract: Synthesis, structure, and theoretical investigation of amidinato supported 1,4-disilabenzene

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Publication details

The article was received on 05 Jun 2010, accepted on 18 Jun 2010 and first published on 09 Jul 2010


Article type: Communication
DOI: 10.1039/C0CC01753A
Citation: Chem. Commun., 2010,46, 5873-5875
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    Synthesis, structure, and theoretical investigation of amidinato supported 1,4-disilabenzene

    S. S. Sen, H. W. Roesky, K. Meindl, D. Stern, J. Henn, A. C. Stückl and D. Stalke, Chem. Commun., 2010, 46, 5873
    DOI: 10.1039/C0CC01753A

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