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Issue 35, 2010
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Complete determination of natural site-specific enantio-isotopomeric excesses in linoleic acid using natural abundance deuterium 2D NMR in polypeptide mesophases

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Abstract

NAD 2D NMR spectroscopy using chiral mesophases made of poly-γ-benzyl-L-glutamate and pyridine allowed us to evaluate, for the first time, the natural site-specific enantio-isotopomeric excesses at each methylene group of linoleic acid, a central, essential PUFA precursor of all conjugated triene fatty acids.

Graphical abstract: Complete determination of natural site-specific enantio-isotopomeric excesses in linoleic acid using natural abundance deuterium 2D NMR in polypeptide mesophases

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Publication details

The article was received on 19 May 2010, accepted on 02 Jul 2010 and first published on 19 Aug 2010


Article type: Communication
DOI: 10.1039/C0CC01486A
Citation: Chem. Commun., 2010,46, 6599-6601
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    Complete determination of natural site-specific enantio-isotopomeric excesses in linoleic acid using natural abundance deuterium 2D NMR in polypeptide mesophases

    Z. Serhan, L. Martel, I. Billault and P. Lesot, Chem. Commun., 2010, 46, 6599
    DOI: 10.1039/C0CC01486A

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