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Issue 34, 2010
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Flexibility of cubane-like Cu4I4 framework: temperature dependence of molecular structure and luminescence thermochromism of [Cu4I4(PPh3)4] in two polymorphic crystalline states

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Abstract

Multitemperature X-ray structure analyses and photoemission spectra of [Cu4I4(PPh3)4] in two polymorphic crystals reveal that the cubane-like framework is flexibly distorted effecting luminescence thermochromism.

Graphical abstract: Flexibility of cubane-like Cu4I4 framework: temperature dependence of molecular structure and luminescence thermochromism of [Cu4I4(PPh3)4] in two polymorphic crystalline states

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Publication details

The article was received on 17 May 2010, accepted on 25 Jun 2010 and first published on 29 Jul 2010


Article type: Communication
DOI: 10.1039/C0CC01434F
Citation: Chem. Commun., 2010,46, 6302-6304
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    Flexibility of cubane-like Cu4I4 framework: temperature dependence of molecular structure and luminescence thermochromism of [Cu4I4(PPh3)4] in two polymorphic crystalline states

    H. Kitagawa, Y. Ozawa and K. Toriumi, Chem. Commun., 2010, 46, 6302
    DOI: 10.1039/C0CC01434F

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