Issue 32, 2010
From the journal:

Chemical Communications

Cobalt-catalyzed C–SMe bond activation of heteroaromatic thioethers†

Jeanne-Marie Begouin,ab   Michael Rivardb  and  Corinne Gosmini*a  

* Corresponding authors

a Laboratoire « Hétéroéléments et Coordination », Ecole Polytechnique, CNRS, 91128 Palaiseau Cedex, France
E-mail: corinne.gosmini@polytechnique.edu
Fax: (+33) 1-6933-4440
Tel: (+33) 1-6933-4412

b Equipe Electrochimie et Synthèse Organique, Institut de Chimie et des Materiaux Paris Est, ICMPE, C.N.R.S.-Université Pari-Est Créteil, UMR 7182, 2, rue Henri Dunant, 94320 Thiais, France

Abstract

Cobalt-catalyzed activation of methylthio-substituted N-heterocycles facilitates either cross-coupling reactions with aryl- or benzylzinc compounds or synthesis of the corresponding zinc compounds.

Graphical abstract: Cobalt-catalyzed C–SMe bond activation of heteroaromatic thioethers

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Article information

DOI
https://doi.org/10.1039/C0CC01055C
Article type
Communication
Submitted
21 Apr 2010
Accepted
15 Jun 2010
First published
12 Jul 2010

Chem. Commun., 2010,46, 5972-5974

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Cobalt-catalyzed C–SMe bond activation of heteroaromatic thioethers

J. Begouin, M. Rivard and C. Gosmini, Chem. Commun., 2010, 46, 5972 DOI: 10.1039/C0CC01055C

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