Issue 36, 2010

Cu and Ag catalyzed oxidative arylthiation of terminal acetylenes

Abstract

A mild Cu or Ag catalyzed oxidative arylthiation of terminal acetylenes is introduced. The process, featuring metal catalyzed C–H bond activation as a key step, leads to the formation of highly substituted mercaptoacetylenes under unprecedented neutral conditions.

Graphical abstract: Cu and Ag catalyzed oxidative arylthiation of terminal acetylenes

Supplementary files

Article information

Article type
Communication
Submitted
12 Apr 2010
Accepted
29 Jun 2010
First published
17 Aug 2010

Chem. Commun., 2010,46, 6819-6821

Cu and Ag catalyzed oxidative arylthiation of terminal acetylenes

A. Henke and J. Srogl, Chem. Commun., 2010, 46, 6819 DOI: 10.1039/C0CC00885K

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