Issue 27, 2010

Stoichiometric and catalyticSn-mediated dehydrocoupling of primary phosphines

Abstract

The room-temperature reactions of stannocene, Cp*2Sn, with a range of primary phosphines, RPH2, result in diphosphanes [RP(H)P(H)R]. The reactions involving Cp*2SnCl2, however, result in catalytic dehydrocoupling; the first example of main group metal catalysed dehydrocoupling to be identified.

Graphical abstract: Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines

Supplementary files

Article information

Article type
Communication
Submitted
08 Apr 2010
Accepted
13 May 2010
First published
03 Jun 2010

Chem. Commun., 2010,46, 5000-5002

Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines

V. Naseri, R. J. Less, R. E. Mulvey, M. McPartlin and D. S. Wright, Chem. Commun., 2010, 46, 5000 DOI: 10.1039/C0CC00827C

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