Issue 25, 2010

Iron(ii)–bis(isonitrile) complexes: novel catalysts in asymmetric transfer hydrogenations of aromatic and heteroaromatic ketones

Abstract

Chiral iron(II)−bis(isonitrile) complexes catalyse the transfer hydrogenation of aromatic ketones with enantioselectivities up to 91% ee, most likely via hydride transfer through imine intermediates, generated by in situ reduction of the isonitrile ligands, whereas iron acts as a Lewis acid to activate the ketone.

Graphical abstract: Iron(ii)–bis(isonitrile) complexes: novel catalysts in asymmetric transfer hydrogenations of aromatic and heteroaromatic ketones

Supplementary files

Additions and corrections

Article information

Article type
Communication
Submitted
20 Mar 2010
Accepted
06 May 2010
First published
20 May 2010

Chem. Commun., 2010,46, 4475-4477

Iron(II)bis(isonitrile) complexes: novel catalysts in asymmetric transfer hydrogenations of aromatic and heteroaromatic ketones

A. Naik, T. Maji and O. Reiser, Chem. Commun., 2010, 46, 4475 DOI: 10.1039/C0CC00508H

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