Issue 29, 2010
From the journal:

Chemical Communications

Core–shell structured microcapsular-like Ru@SiO2 reactor for efficient generation of COx-free hydrogen through ammoniadecomposition†

Yanxing Li,ab   Lianghong Yao,a   Yanyan Song,a   Shunqiang Liu,a   Jing Zhao,a   Weijie Ji*a  and  Chak-Tong Au*b  

* Corresponding authors

a Key Laboratory of Mesoscopic Chemistry, MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China
E-mail: jiwj@nju.edu.cn
Fax: +86-25-83317761

b Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong
E-mail: pctau@hkbu.edu.hk
Fax: +852-34117348

Abstract

The core–shell structured microcapsular-like Ru@SiO2 reactor is proved to be the most efficient material known to date for COx-free hydrogen production via ammonia decomposition for fuel cells application. The very active Ru core particles can retain good stability even at high temperatures (up to 650 °C) thanks to the protection of the inert SiO2 nano-shell.

Graphical abstract: Core–shell structured microcapsular-like Ru@SiO2 reactor for efficient generation of COx-free hydrogen through ammonia decomposition

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Article information

DOI
https://doi.org/10.1039/C0CC00430H
Article type
Communication
Submitted
17 Mar 2010
Accepted
19 May 2010
First published
14 Jun 2010

Chem. Commun., 2010,46, 5298-5300

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Core–shell structured microcapsular-like Ru@SiO2 reactor for efficient generation of COx-free hydrogen through ammonia decomposition

Y. Li, L. Yao, Y. Song, S. Liu, J. Zhao, W. Ji and C. Au, Chem. Commun., 2010, 46, 5298 DOI: 10.1039/C0CC00430H

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