Issue 21, 2010

Modulable cooperativity in a valence tautomeric complex functionalized with branched alkyl chains

Abstract

Functionalization of a cobalt/dioxolene complex with branched, asymmetric alkyl chains promotes non-cooperative and cooperative valence tautomerisms synchronized with thermodynamically favoured crystal-to-melt and kinetically generated glass-to-melt phase transitions, respectively, depending on the degree of crystallinity.

Graphical abstract: Modulable cooperativity in a valence tautomeric complex functionalized with branched alkyl chains

Supplementary files

Article information

Article type
Communication
Submitted
27 Jan 2010
Accepted
09 Mar 2010
First published
09 Apr 2010

Chem. Commun., 2010,46, 3729-3731

Modulable cooperativity in a valence tautomeric complex functionalized with branched alkyl chains

D. Kiriya, K. Nakamura, S. Kitagawa and H. Chang, Chem. Commun., 2010, 46, 3729 DOI: 10.1039/C001568G

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