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Issue 12, 2010
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A new special pair model comprising meso-di-p-anisylaminoporphyrin: enhancement of visible-light absorptivities and quantification of electronic communication in mixed-valent cation radical

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Abstract

Slipped cofacial porphyrin dimer 12 with di-p-anisylamino groups on the meso-positions shows characteristic photo- and electroproperties making it suitable as a photosynthetic special pair model: more intense and red-shifted absorptivities in the visible region, and electronic communication between the two porphyrins in mixed-valent cation radical 12+, which is quantified with an IVCT band analysis.

Graphical abstract: A new special pair model comprising meso-di-p-anisylaminoporphyrin: enhancement of visible-light absorptivities and quantification of electronic communication in mixed-valent cation radical

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Publication details

The article was received on 13 Nov 2009, accepted on 22 Jan 2010 and first published on 10 Feb 2010


Article type: Communication
DOI: 10.1039/B923854A
Citation: Chem. Commun., 2010,46, 2028-2030
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    A new special pair model comprising meso-di-p-anisylaminoporphyrin: enhancement of visible-light absorptivities and quantification of electronic communication in mixed-valent cation radical

    R. Sakamoto, M. Nishikawa, T. Yamamura, S. Kume and H. Nishihara, Chem. Commun., 2010, 46, 2028
    DOI: 10.1039/B923854A

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