Issue 11, 2010
From the journal:

Chemical Communications

Synthesis and characterization of a tin(ii) bis(phosphinoyl)methanediide complex: a stannavinylidene derivative†

Jiayi Guo,a   Kai-Chung Lau,b   Hong-Wei Xi,c   Kok Hwa Limc  and  Cheuk-Wai So*a  

* Corresponding authors

a Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371 Singapore
E-mail: CWSo@ntu.edu.sg
Fax: +65 6791 1961
Tel: +65 6513 2730

b Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong

c Division of Chemical and Biomolecular Engineering, School of Chemical and Biomedical Engineering, Nanyang Technological University, 637459 Singapore

Abstract

The reaction of [CH2(PPh2[double bond, length as m-dash]NSiMe3)(PPh2[double bond, length as m-dash]S)] (1) with two equivalents of [Sn{N(SiMe3)2}2] in refluxing toluene afforded novel tin(II) bis(phosphinoyl)methanediide complex 3. The structure of compound 3 has been determined by X-ray crystallography and DFT calculations. The topological analysis of the electron densities of compound 3 was performed.

Graphical abstract: Synthesis and characterization of a tin(ii) bis(phosphinoyl)methanediide complex: a stannavinylidene derivative

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Article information

DOI
https://doi.org/10.1039/B922377K
Article type
Communication
Submitted
27 Oct 2009
Accepted
26 Jan 2010
First published
09 Feb 2010

Chem. Commun., 2010,46, 1929-1931

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Synthesis and characterization of a tin(II) bis(phosphinoyl)methanediide complex: a stannavinylidene derivative

J. Guo, K. Lau, H. Xi, K. H. Lim and C. So, Chem. Commun., 2010, 46, 1929 DOI: 10.1039/B922377K

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