Issue 9, 2010
From the journal:

Chemical Communications

Stabilising a quinonoid-bridged dicopper(i) complex by use of a dppf (dppf = (diphenylphosphino)ferrocene) backbone†

Alexa Paretzki,a   Roberto Pattacini,b   Ralph Huebner,a   Pierre Braunstein*b  and  Biprajit Sarkar*a  

* Corresponding authors

a Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, Stuttgart, Germany
E-mail: sarkar@iac.uni-stuttgart.de
Fax: (+)4971168564165
Tel: (+)4971168564235

b Laboratoire de Chimie de Coordination, Institut de Chimie (UMR 7177 CNRS), Université de Strasbourg, 4 rue Blaise Pascal, Strasbourg Cédex, France
E-mail: braunstein@unistra.fr
Fax: (+)33368851322
Tel: (+)33368851308

Abstract

An unprecedented quinonoid-bridged dicopper(I) complex is described together with its redox, EPR and structural properties, which indicate a non-innocent role of the zwitterion-derived bridging ligand.

Graphical abstract: Stabilising a quinonoid-bridged dicopper(i) complex by use of a dppf (dppf = (diphenylphosphino)ferrocene) backbone

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Article information

DOI
https://doi.org/10.1039/B921731B
Article type
Communication
Submitted
16 Oct 2009
Accepted
02 Dec 2009
First published
23 Dec 2009

Chem. Commun., 2010,46, 1497-1499

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Stabilising a quinonoid-bridged dicopper(I) complex by use of a dppf (dppf = (diphenylphosphino)ferrocene) backbone

A. Paretzki, R. Pattacini, R. Huebner, P. Braunstein and B. Sarkar, Chem. Commun., 2010, 46, 1497 DOI: 10.1039/B921731B

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