Issue 10, 2010
From the journal:

Chemical Communications

Platinum-catalysed diborylation of arynes: synthesis and reaction of 1,2-diborylarenes†

Hiroto Yoshida,*a   Kengo Okada,a   Shota Kawashima,a   Kenji Taninoa  and  Joji Ohshitaa  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan
E-mail: yhiroto@hiroshima-u.ac.jp
Fax: +81-82-424-5494
Tel: +81-82-424-7724

Abstract

Arynes are found to be facilely inserted into bis(pinacolato)diboron by using a platinum–isocyanide catalyst, affording diverse 1,2-diborylarenes, which can be converted into o-terphenyls via Suzuki–Miyaura coupling reaction.

Graphical abstract: Platinum-catalysed diborylation of arynes: synthesis and reaction of 1,2-diborylarenes

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Article information

DOI
https://doi.org/10.1039/B919407J
Article type
Communication
Submitted
17 Sep 2009
Accepted
25 Nov 2009
First published
13 Jan 2010

Chem. Commun., 2010,46, 1763-1765

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Platinum-catalysed diborylation of arynes: synthesis and reaction of 1,2-diborylarenes

H. Yoshida, K. Okada, S. Kawashima, K. Tanino and J. Ohshita, Chem. Commun., 2010, 46, 1763 DOI: 10.1039/B919407J

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