Tetrasubstituted allenes by Pd0-catalyzed three-component tandem Michael addition/cross-coupling reaction

Yuanjing Xiao; Junliang Zhang

doi:10.1039/B919060K

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Tetrasubstituted allenes by Pd⁰-catalyzed three-component tandem Michael addition/cross-coupling reaction†

Yuanjing Xiao^a and Junliang Zhang*^ab

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* Corresponding authors

^a Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 N, Zhongshan Road, Shanghai 200062, P. R. China
E-mail: jlzhang@chem.ecnu.edu.cn
Fax: (+86) 21-6223-5039

^b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, P. R. China

Abstract

A Pd⁰-catalyzed three-component tandem Michael addition/cross-coupling reaction of electron-deficient enynes with nucleophiles and aryl halides was developed, which provides general, efficient, and regioselective access to multi-functionalized tetra-substituted allenes.

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Article information

DOI: https://doi.org/10.1039/B919060K
Article type: Communication
Submitted: 15 Sep 2009
Accepted: 12 Nov 2009
First published: 27 Nov 2009

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Chem. Commun., 2010,46, 752-754

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Tetrasubstituted allenes by Pd⁰-catalyzed three-component tandem Michael addition/cross-coupling reaction

Y. Xiao and J. Zhang, Chem. Commun., 2010, 46, 752 DOI: 10.1039/B919060K

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