Issue 48, 2009

Synthesis of transition metal isocyanide compounds from carbonyl complexes via reaction with Li[Me3SiNR]

Abstract

The reaction between a transition metal carbonyl compound, LnMCO, and Li[Me3SiNR] yields the corresponding isocyanide derivative, LnMCNR, thereby providing a new route to transition metal isocyanide compounds that does not require the use of free isocyanides as reagents.

Graphical abstract: Synthesis of transition metal isocyanide compounds from carbonyl complexes via reaction with Li[Me3SiNR]

Supplementary files

Article information

Article type
Communication
Submitted
19 Aug 2009
Accepted
12 Oct 2009
First published
12 Nov 2009

Chem. Commun., 2009, 7566-7568

Synthesis of transition metal isocyanide compounds from carbonyl complexes via reaction with Li[Me3SiNR]

W. Sattler and G. Parkin, Chem. Commun., 2009, 7566 DOI: 10.1039/B917156H

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