Issue 37, 2009
From the journal:

Chemical Communications

Oligosilylated group 4 titanocenes in the oxidation state +3†

Michaela Zirngast,a   Ulrich Flörke,b   Judith Baumgartner*a  and  Christoph Marschner*a  

* Corresponding authors

a Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 16, 8010 Graz, Austria
E-mail: baumgartner@tugraz.at, christoph.marschner@tugraz.at
Fax: +43 316 873 8701
Tel: +43 316 873 8209

b Anorganische und Analytische Chemie, Universität Paderborn, Warburger Str. 100, 33098-Paderborn, Germany

Abstract

Reactions of oligosilylanions with Cp2TiCl2 led to the formation of ate-complexes of silylated titanocenes, which form upon silylation of the intermediate K[Cp2TiCl2]·18-crown-6.

Graphical abstract: Oligosilylated group 4 titanocenes in the oxidation state +3

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Article information

DOI
https://doi.org/10.1039/B910637E
Article type
Communication
Submitted
29 May 2009
Accepted
10 Jul 2009
First published
13 Aug 2009

Chem. Commun., 2009, 5538-5540

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Oligosilylated group 4 titanocenes in the oxidation state +3

M. Zirngast, U. Flörke, J. Baumgartner and C. Marschner, Chem. Commun., 2009, 5538 DOI: 10.1039/B910637E

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