Issue 25, 2009
From the journal:

Chemical Communications

The oxidation of Ni(ii) N-confused porphyrins (NCPs) with azo radical initiators and an unexpected intramolecular nucleophilic substitution reactionvia a proposed Ni(iii) NCP intermediate†

Hua-Wei Jiang,a   Qing-Yun Chen,a   Ji-Chang Xiao*a  and  Yu-Cheng Gub  

* Corresponding authors

a Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, P. R. China
E-mail: jchxiao@mail.sioc.ac.cn
Fax: (+86) 21-6416 6128

b Syngenta, Jealott’s Hill International Research Centre, Bracknell, Berkshire, UK

Abstract

The oxidation of Ni(II) N-confused porphyrins (NCPs) with azo radical initiators resulted in an unexpected intramolecular nucleophilic substitution reactionvia a proposed Ni(III) NCP intermediate, which could be detected by HRMS.

Graphical abstract: The oxidation of Ni(ii) N-confused porphyrins (NCPs) with azo radical initiators and an unexpected intramolecular nucleophilic substitution reactionvia a proposed Ni(iii) NCP intermediate

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Article information

DOI
https://doi.org/10.1039/B904615A
Article type
Communication
Submitted
05 Mar 2009
Accepted
27 Apr 2009
First published
15 May 2009

Chem. Commun., 2009, 3732-3734

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The oxidation of Ni(II) N-confused porphyrins (NCPs) with azo radical initiators and an unexpected intramolecular nucleophilic substitution reactionvia a proposed Ni(III) NCP intermediate

H. Jiang, Q. Chen, J. Xiao and Y. Gu, Chem. Commun., 2009, 3732 DOI: 10.1039/B904615A

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