Issue 13, 2009
From the journal:

Chemical Communications

Quantitative formation of [4]pseudorotaxanes from two rods and two bis-macrocycles incorporating porphyrinic plates between the rings†‡

Jean-Paul Collin,*a   Fabien Durola,a   Julien Frey,a   Valérie Heitz,*a   Jean-Pierre Sauvage,*a   Christian Tocka  and  Yann Troleza  

* Corresponding authors

a Laboratoire de Chimie Organo-Minérale, Institut de Chimie, LC3 UMR 7177 du CNRS, Université de Strasbourg, 4 rue Blaise Pascal, 67070 Strasbourg Cedex, France
E-mail: sauvage@chimie.u-strasbg.fr, jpcollin@chimie.u-strasbg.fr, heitz@chimie.u-strasbg.fr
Fax: 33(0)3 90 24 13 68
Tel: 33(0)3 90 24 13 61

Abstract

[4]Pseudorotaxanes consisting of two very large coordinating bis-macrocycles and rigid rods incorporating two side-by-side chelates have been obtained quantitatively utilising the gathering and threading effect of copper(I); the assemblies obtained are several nanometres long and they contain two face-to-face zinc porphyrins which will be used to complex various organic substrates.

Graphical abstract: Quantitative formation of [4]pseudorotaxanes from two rods and two bis-macrocycles incorporating porphyrinic plates between the rings

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Article information

DOI
https://doi.org/10.1039/B901482A
Article type
Communication
Submitted
22 Jan 2009
Accepted
11 Feb 2009
First published
26 Feb 2009

Chem. Commun., 2009, 1706-1708

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Quantitative formation of [4]pseudorotaxanes from two rods and two bis-macrocycles incorporating porphyrinic plates between the rings

J. Collin, F. Durola, J. Frey, V. Heitz, J. Sauvage, C. Tock and Y. Trolez, Chem. Commun., 2009, 1706 DOI: 10.1039/B901482A

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