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Issue 24, 2009
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Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes

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Abstract

The rhodium-catalyzed intermolecular asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes gave chiral allylicphosphine oxides substituted with vinylether and thioether moieties in high yields with high enantioselectivities.

Graphical abstract: Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes

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Publication details

The article was received on 16 Jan 2009, accepted on 17 Feb 2009 and first published on 13 Mar 2009


Article type: Communication
DOI: 10.1039/B900976K
Citation: Chem. Commun., 2009,0, 3528-3530
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    Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes

    T. Kawamoto, S. Hirabayashi, X. Guo, T. Nishimura and T. Hayashi, Chem. Commun., 2009, 0, 3528
    DOI: 10.1039/B900976K

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