Issue 29, 2009
From the journal:

Chemical Communications

A four-shell, 136-metal 3d-4f heterometallic cluster approximating a rectangular parallelepiped†

Xiang-Jian Kong,ab   La-Sheng Long,*a   Rong-Bin Huang,a   Lan-Sun Zheng,a   T. David Harrisc  and  Zhiping Zheng*ab  

* Corresponding authors

a State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, China
E-mail: lslong@xmu.edu.cn
Fax: 86-592-2183047

b Department of Chemistry, University of Arizona, Tucson, Arizona 85721, USA
E-mail: zhiping@u.arizona.edu
Fax: +1 (520)-621-8407

c Department of Chemistry, University of California, Berkeley, CA 94720-1460, USA

Abstract

A nanosized heterometallic cluster containing 60 La(III) and 76 Ni(II) ions, which are arranged into a four-shell, nest-like framework structure, was obtained by the hydrolytic reaction of the mixed La(NO3)3–Ni(NO3)2 system using iminodiacetate as an ancillary ligand to control the hydrolysis.

Graphical abstract: A four-shell, 136-metal 3d-4f heterometallic cluster approximating a rectangular parallelepiped

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Article information

DOI
https://doi.org/10.1039/B822609A
Article type
Communication
Submitted
16 Dec 2008
Accepted
20 Mar 2009
First published
06 Apr 2009

Chem. Commun., 2009, 4354-4356

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A four-shell, 136-metal 3d-4f heterometallic cluster approximating a rectangular parallelepiped

X. Kong, L. Long, R. Huang, L. Zheng, T. D. Harris and Z. Zheng, Chem. Commun., 2009, 4354 DOI: 10.1039/B822609A

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