Issue 14, 2009
From the journal:

Chemical Communications

1D Infinite silver(i) chains reside in the big cavities built by the novel p-sulfonatocalix[4]arene-trisilver blocks†

Kecai Xiong,ab   Mingyan Wu,a   Qingfu Zhang,ab   Wei Wei,ab   Ming Yang,ab   Feilong Jiang*a  and  Maochun Hong*a  

* Corresponding authors

a State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China
E-mail: fjiang@fjirsm.ac.cn, hmc@fjirsm.ac.cn
Fax: +86-591-83794946
Tel: +86-591-83714605

b Graduate School of the Chinese Academy of Sciences, Beijing, China

Abstract

A novel luminescent inclusion complex, {[(C4AS)2Ag3(μ-2,2′-bpy)2(2,2′-bpy)2] [Ag5(μ-2,2′-bpy)4(2,2′-bpy)4]·20H2O}n (1) (2,2′-bpy = 2,2′-bipyridine, C4AS = p-sulfonatocalix[4]arene), with an unusual framework is reported: the parallel 1D infinite silver(I) chains separated by the water belts reside in the big cavities of the p-sulfonatocalix[4]arene-trisilver blocks.

Graphical abstract: 1D Infinite silver(i) chains reside in the big cavities built by the novel p-sulfonatocalix[4]arene-trisilver blocks

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Article information

DOI
https://doi.org/10.1039/B821961C
Article type
Communication
Submitted
08 Dec 2008
Accepted
21 Jan 2009
First published
18 Feb 2009

Chem. Commun., 2009, 1840-1842

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1D Infinite silver(I) chains reside in the big cavities built by the novel p-sulfonatocalix[4]arene-trisilver blocks

K. Xiong, M. Wu, Q. Zhang, W. Wei, M. Yang, F. Jiang and M. Hong, Chem. Commun., 2009, 1840 DOI: 10.1039/B821961C

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