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Issue 14, 2009
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1D Infinite silver(I) chains reside in the big cavities built by the novel p-sulfonatocalix[4]arene-trisilver blocks

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Abstract

A novel luminescent inclusion complex, {[(C4AS)2Ag3(μ-2,2′-bpy)2(2,2′-bpy)2] [Ag5(μ-2,2′-bpy)4(2,2′-bpy)4]·20H2O}n (1) (2,2′-bpy = 2,2′-bipyridine, C4AS = p-sulfonatocalix[4]arene), with an unusual framework is reported: the parallel 1D infinite silver(I) chains separated by the water belts reside in the big cavities of the p-sulfonatocalix[4]arene-trisilver blocks.

Graphical abstract: 1D Infinite silver(i) chains reside in the big cavities built by the novel p-sulfonatocalix[4]arene-trisilver blocks

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Publication details

The article was received on 08 Dec 2008, accepted on 21 Jan 2009 and first published on 18 Feb 2009


Article type: Communication
DOI: 10.1039/B821961C
Citation: Chem. Commun., 2009, 1840-1842
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    1D Infinite silver(I) chains reside in the big cavities built by the novel p-sulfonatocalix[4]arene-trisilver blocks

    K. Xiong, M. Wu, Q. Zhang, W. Wei, M. Yang, F. Jiang and M. Hong, Chem. Commun., 2009, 1840
    DOI: 10.1039/B821961C

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