Jump to main content
Jump to site search

Issue 19, 2009
Previous Article Next Article

Unusual H-bonding in novel cyano-cluster polymeric hydrates [(H){Ln(H2O)4}{Re6S8(CN)6}]·2H2O (Ln = Yb, Lu)

Author affiliations

Abstract

X-Ray studies and 1H NMR measurements for novel cyano-bridged polymers [(H){Ln(H2O)4}{Re6S8(CN)6}]·2H2O (Ln = Yb, Lu) reveal temperature dependence of proton localization: acid protons are trapped between nitrogen atoms at low temperatures, but can be transferred to the water sublattice at higher temperatures; this transfer resulted in intermolecular proton exchange.

Graphical abstract: Unusual H-bonding in novel cyano-cluster polymeric hydrates [(H){Ln(H2O)4}{Re6S8(CN)6}]·2H2O (Ln = Yb, Lu)

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 19 Nov 2008, accepted on 23 Feb 2009 and first published on 20 Mar 2009


Article type: Communication
DOI: 10.1039/B820722D
Citation: Chem. Commun., 2009, 2655-2657
  •   Request permissions

    Unusual H-bonding in novel cyano-cluster polymeric hydrates [(H){Ln(H2O)4}{Re6S8(CN)6}]·2H2O (Ln = Yb, Lu)

    M. S. Tarasenko, E. O. Golenkov, N. G. Naumov, N. K. Moroz and V. E. Fedorov, Chem. Commun., 2009, 2655
    DOI: 10.1039/B820722D

Search articles by author