Issue 12, 2009
From the journal:

Chemical Communications

Formation of pentacyclic structures by a domino sequence on cyclic enamides†

Gedu Satyanarayana,a   Caecilia Maichle-Mössmer‡b  and  Martin E. Maier*a  

* Corresponding authors

a Institut für Organische Chemie, Universität Tübingen, Auf der Morgenstelle 18, Tübingen, Germany
E-mail: martin.e.maier@uni-tuebingen.de
Fax: +49 7071 5137
Tel: +49 7071-2975247

b Institut für Anorganische Chemie, Universität Tübingen, Auf der Morgenstelle 18, Tübingen, Germany

Abstract

Novel spiropentacyclic compounds 11 were obtained from cyclic enamides of type 9, featuring a (2-bromophenyl)propyl substituent in the 5-position, through a Pd-mediated domino sequence taking place viaHeck insertion and C–H activation.

Graphical abstract: Formation of pentacyclic structures by a domino sequence on cyclic enamides

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Article information

DOI
https://doi.org/10.1039/B820636H
Article type
Communication
Submitted
18 Nov 2008
Accepted
06 Jan 2009
First published
30 Jan 2009

Chem. Commun., 2009, 1571-1573

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Formation of pentacyclic structures by a domino sequence on cyclic enamides

G. Satyanarayana, C. Maichle-Mössmer and M. E. Maier, Chem. Commun., 2009, 1571 DOI: 10.1039/B820636H

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