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Issue 15, 2009
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A metal–organic framework based on an unprecedented nonanuclear cluster as a secondary building unit: structure and gas sorption behavior

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Abstract

A 3D chiral microporous metal–organic framework containing a nonanuclear cluster as a secondary building unit was prepared using a bent and rigid dicarboxylic ligand, 2,7-naphthalene dicarboxylic acid, and the zinc ion, where a nonanuclear cluster with potential exposed metal sites is in the form of a corner-sharing cyclic trimer of a tetrahedral Zn4O motif.

Graphical abstract: A metal–organic framework based on an unprecedented nonanuclear cluster as a secondary building unit: structure and gas sorption behavior

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Publication details

The article was received on 21 Oct 2008, accepted on 04 Feb 2009 and first published on 26 Feb 2009


Article type: Communication
DOI: 10.1039/B818648K
Citation: Chem. Commun., 2009,0, 2026-2028
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    A metal–organic framework based on an unprecedented nonanuclear cluster as a secondary building unit: structure and gas sorption behavior

    M. Park, D. Moon, J. W. Yoon, J. Chang and M. S. Lah, Chem. Commun., 2009, 0, 2026
    DOI: 10.1039/B818648K

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