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Issue 1, 2009
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Gallyl lanthanide complexes containing unsupported Ln–Ga (Ln = Sm, Eu, Yb or Tm) bonds

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Abstract

A series of bis(gallyl) lanthanide(II) complexes, [LnII{Ga[(ArNCH)2]}2(tmeda)2] (Ln = Sm, Eu or Yb; Ar = C6H3Pri2-2,6), and a gallyl thulium(III) compound, [TmIII{Ga[(ArNCH)2]}{(ArNCH)2}(tmeda)], have been prepared; the first structural studies of Ga–Tm and Ga–Sm bonded complexes are described.

Graphical abstract: Gallyl lanthanide complexes containing unsupported Ln–Ga (Ln = Sm, Eu, Yb or Tm) bonds

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Publication details

The article was received on 13 Oct 2008, accepted on 05 Nov 2008 and first published on 12 Nov 2008


Article type: Communication
DOI: 10.1039/B817933F
Citation: Chem. Commun., 2009, 113-115
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    Gallyl lanthanide complexes containing unsupported Ln–Ga (Ln = Sm, Eu, Yb or Tm) bonds

    C. Jones, A. Stasch and W. D. Woodul, Chem. Commun., 2009, 113
    DOI: 10.1039/B817933F

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