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Issue 47, 2008
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Asymmetric organocatalytic Michael addition of ketones to vinylsulfone

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Abstract

Highly enantioselective organocatalytic Michael addition of ketones to vinylsulfone catalyzed by a cinchona alkaloid-derived primary amine is reported for the first time; the described synthetic methodology was applied to the synthesis of sodium cyclamate.

Graphical abstract: Asymmetric organocatalytic Michael addition of ketones to vinylsulfone

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Publication details

The article was received on 17 Sep 2008, accepted on 10 Oct 2008 and first published on 05 Nov 2008


Article type: Communication
DOI: 10.1039/B816307C
Citation: Chem. Commun., 2008, 6315-6317
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    Asymmetric organocatalytic Michael addition of ketones to vinylsulfone

    Q. Zhu, L. Cheng and Y. Lu, Chem. Commun., 2008, 6315
    DOI: 10.1039/B816307C

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