Issue 47, 2008
From the journal:

Chemical Communications

Adding to the confusion! Synthesis and metalation of pyrazole analogues of the porphyrins†

Timothy D. Lash,*a   Alexandra M. Young,a   Amber L. Von Rudena  and  Gregory M. Ferrencea  

* Corresponding authors

a Department of Chemistry, Illinois State University, Normal, Illinois, USA
E-mail: tdlash@ilstu.edu
Fax: +1 309 438-8554

Abstract

N-substituted pyrazoledialdehydes are shown to react with a tripyrrane under ‘3 + 1’ conditions to give aza-analogues of the N-confused porphyrins; these novel porphyrinoids show borderline aromatic properties and readily afford organometallic derivatives with Ni(OAc)2 and Pd(OAc)2.

Graphical abstract: Adding to the confusion! Synthesis and metalation of pyrazole analogues of the porphyrins

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B816057K
Article type
Communication
Submitted
15 Sep 2008
Accepted
03 Oct 2008
First published
07 Nov 2008

Chem. Commun., 2008, 6309-6311

Permissions

Request permissions

Adding to the confusion! Synthesis and metalation of pyrazole analogues of the porphyrins

T. D. Lash, A. M. Young, A. L. Von Ruden and G. M. Ferrence, Chem. Commun., 2008, 6309 DOI: 10.1039/B816057K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements